Aus der Theorie der Orbitalwechselwirkung lassen sich grundlegende Prinzipien der chemischen Reaktivit???t anhand elektronischer Strukturmerkmale erkl???ren und verallgemeinern. Auf dieser Grundlage kann man auf die thermodynamische und kinetische Stabilit???t von Verbindungen zur???ckschlie???en. Alle wesentlichen Aspekte der Methode sind Gegenstand dieses Bandes, dessen 2. Auflage rund ein Drittel mehr Material enth???lt als die Erstauflage. Geboten wird ein neues Kapitel ???ber Organometallverbindungen und eine ...
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Aus der Theorie der Orbitalwechselwirkung lassen sich grundlegende Prinzipien der chemischen Reaktivit???t anhand elektronischer Strukturmerkmale erkl???ren und verallgemeinern. Auf dieser Grundlage kann man auf die thermodynamische und kinetische Stabilit???t von Verbindungen zur???ckschlie???en. Alle wesentlichen Aspekte der Methode sind Gegenstand dieses Bandes, dessen 2. Auflage rund ein Drittel mehr Material enth???lt als die Erstauflage. Geboten wird ein neues Kapitel ???ber Organometallverbindungen und eine erweiterte Diskussion der Dichtefunktionaltheorie. Aktuellste Rechenmethoden werden an Beispielen anschaulich demonstriert. (12/00)
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